cant speak for the standalone pcsx-rearmed so someone else could probly chip in there as for the libretro build its possible to generate game specific overides both for core settings and controller remaps via the quick menu section of emulators menu i use the libretro build myself for specific core settings for certan games as analogue input breaks certan games and enhanced resolution brings in graphic glitches on some too so i have specific configs for these games via the override feature